Product ID:MIL-C-46168D, PART B 4:1 BLEND
MSDS Date:11/17/1988
FSC:8010
NIIN:01-130-3345
Kit Part:Y
MSDS Number: BHNDM

NILES CHEMICAL PAINT COMPANY

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5856 (24 HOURS)

Info Phone: 616-683-3377 (INFORMATION)

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

HOMOPOLYMER OF HDI

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 75%

1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE)

CAS: 822-06-0

RTECS: MO1740000

Fraction By Weight: 0.7%

ACGIH TLV: 0.005 PPM; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 12.5%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 12.5%

OSHA PEL 150 PPM/200 STEL

ACGIH TLV: 150 PPM/200STEL;9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

VOC. ORGANIC CMPD 2.21 LB/GAL

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EXPOSURE MAY LEAD TO BRONCHITIS,
BRONCHIAL SPASM, & PULMONARY EDEMA. CHEMICAL OR HYPERSENSITIVE
PNEUMONITIS W/FLU LIKE SYMPTOMS. VOMITING MAY CAUSE ASPIRATIONOF
THE SOLV RESULTING IN CHEM PNEUMONITI S. CONTACT W/BUTYL ACETATE OR
XYLENECAN RESULT IN DRY,DEFATTED, & CRACKED SKIN CAUSING SUSCEPT.
TO INFECTIONS.
Effects of Overexposure:EYE: IRRIT.,TEARING,REDDENING, & SWELLING ALONG
W/STINGING & DUST SENSATION SKIN:
REDDENING,SWELLING,RASH,SCALING, OR BLISTERING, & DERMATITIS
INHALE:IRRIT. THE MUCOUS MEMBRANES IN NO
SE,THROAT,LUNGS,COUGHING,CHST DISCOMFORTINGEST: IRRIT. & CORROSIVE
ACTION TO MOUTH,STOMACH TISSUE, & DIGESTIVE TRACK.
Medical Cond Aggravated by Exposure:ASTHMA, RESPIRATORY DISORDERS SUCH
AS BRONCHITIS, EMPHYSEMA, & HYPERRACTIVITY, SKIN ALLERGIES, AND
ECZMA.

First Aid:EYE: FLUSH W/CLN LKWRM WTR,LOW PRESS FOR 15 MINS,LIFTING
EYELIDS, GET MED ATTN SKIN: WASH AREA W/SOAP & WTR. REMOVE CONTAM.
CLOTHING IMMED., GET MEDCL ATTN INGST:DO NOT INDUCE VOMITING. DO
NOT GIV E ANYTHING BY MOUTH, CONSULT A PHYSICIANINHALE: REMOVE TO
FRESH AIR,GIVE ARTIFICIAL RESP. AS NEEDED, GET MEDICAL ATTN
ASTHMATIC TYPE SYMPTOMS MAY DEVELOP & MAY BE IMMED. OR DELAYED UP
TO SEVERAL HRS

Flash Point Method:PMCC
Flash Point:91F/33C
Lower Limits:1.0
Upper Limits:7.6
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:WEAR SCBA & FULL PROTECTIVE CLOTHING. ISOLATE
FROM HEAT, ELEC. EQUIP, SPARKS, & OPEN FLAME. CLOSED CONTAINER MAY
EXPLODE WHEN EXP0SED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:BURST WHEN CONTAMINATED WITH WATER
CREATING CO2. STAGNANT AIR MAY CAUSE VAPORS TO BLD UP & TRVL ALNG
GRND TO AN IGN SOURCE W/MAY FLASH BK TO SOURCE OF VAPORS.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION & VENTL AREA.
DIKE OR IMPOUND SPILLED MATL & CONTRL FURTHER SPILLAGE IF
POSS.COLLECT MATL IN OPEN CONTNR TO SAFE PLACE.COVER LOOSELY &
ALLOW TO STAND FOR 24-48 HRS. WASH DOWN SPILL AREAS
W/DECONTAMINATION SOLUTIONS.
Neutralizing Agent:TERGITOL TMN-10(20%)WATER(80%),CONC
AMMONIA(3-8%)DETERGENT(2%)WATER(90-95%)

Handling and Storage Precautions:KEEP AWAY FROM HEAT,SPRKS,& OPEN
FLAME. STORE IN TIGHTLY CLSD CONTNR TO PREVNT MOISTURE CONTAMIN.
IDEAL STORAGE IS 50-81F/10-27C.
Other Precautions:DO NOT RESEAL IF CONTAMINATION IS SUSPECTED. IF
CONTNR IS EXPOSED TO HIGH HEAT, IT CAN BE PRESSURIZED & POSS
RUPTURE EXPLOSIVELY. THIS GAS CAN CAUSE SEALED CONTAINERS TO
EXPAND AND POSSIBLY RUPTUR E EXPLOSIVELY.

Respiratory Protection:POSTV. PRESS. SUPLD AIR RESP. IS MANDATORY FOR
CONFND AREAS. OTHER APPROVED PROTECTION, AIR PURIFYING OR FRESH
AIR SUPPLIED RESPIRATORS.
Ventilation:EXHAUST VENTILATION SUFFICIENT TO KEEP THE AIRBORNE CONCENT
OF THE SOLVENT,HDI, & POLYISOCYANATE BELOW THEIR TLV'S
Protective Gloves:CHEMICAL RESISTANT GLOVES
Eye Protection:SAFETY GLASSES,SPLASH GOGGLES,FACESHIELD
Other Protective Equipment:SAFETY SHOWERS & EYEWASH STATIONS SHOULD BE
AVAILABLE & SHOULD BE USED WHEN NEEDED.
Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING & BEFORE
USING RESTROOMSSMOKE ONLY IN SMOKING AREAS.
Supplemental Safety and Health
COVER AS MUCH OF THE EXPOSED SKIN AREA AS POSSIBLE WITH APPROPRIATE
CLOTHING. IF SKIN CREAMS ARE USED, KEEP THE AREA PROTECTED ONLY BY
THE CREAM TO A MINIMUM.WASH CONTAMINATED CLOTHING THOROUGHLY BE
FORE REUSE.

Boiling Pt:B.P. Text:NE
Vapor Density:> AIR
Viscosity:183 MPAS @20C
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBLE/REACTS WTR
Appearance and Odor:CLEAR TO PALE YELLOW LIQUID WITH SOLVENT ODOR
Percent Volatiles by Volume:30 CA

Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS, AND SURFACE
ACTIVE MATERIALS
Stability Condition to Avoid:MOISTURE, HIGH TEMPERATURES,SHOCK FROM
DROPPING
Hazardous Decomposition Products:BY HIGH HEAT & FIRE: CARBON
IOXIDE/MONOXIDE,OXIDES OF NITRO-GEN, TRACES OF HNC AND HDI
Conditions to Avoid Polymerization:IF IN CONTACT WITH MOISTURE OR OTHER
MATL WHICH REACTS WITH ISOCYANATES. MAY OCCUR AT TEMP >400F/204C

Waste Disposal Methods:DISPOSE IN ACCORDANCE W/FEDERAL, STATE, AND
LOCAL REGULATIONS. INCINERATION IS PREFERRED. EMPTY CON-TAINER MUST
BE HANDLED W/CARE DUE TO PROD RESIDUE & FLAM VAPOR. DO NOT HEAT OR
CUT ON OR NEAR EMPTY CONTAINERS W/ELEC OR GAS TOURCH.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.